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A neo group is a group that has three methyl groups at the end and AT LEAST five carbons total, ie there is a secondary carbon connecting the branching side chain to the main chain. A tert-butyl group is a branching side chain that contains three methyls at the end and connects to the main chain via the tertiary carbon (once it is bonded to the chain, it is quaternary). The tert-butyl group is a sub-class of the neo branching. If you look at the example again, you will see that tert-butyl has FOUR carbons not five and thus could not be neopentyl. You should have the lowest possible sum of the positions of the substituents. This works for the example on page 68 as well.
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The boiling point of substance can be defined as, it is the temperature at which the vapour pressure of the substance equal to atmospheric pressure. According to Raoult's law, the vapour pressure of a solvent decreases in the presence of a non-volatile solute. Thus, the vapour pressure of a solution containing a non-volatile solute requires a high temperature to become equal to the atmospheric pressure. That is why the boiling point of a solution containing a non-volatile solute increases. Thus, the solution containing a non-volatile solute has a higher boiling point than a pure solvent. Example of non-volatile solute sugar, NaCl. etc.
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Shraddha Joshi 6 years, 9 months ago
2Thank You