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Posted by Parvathi G Nair 6 years, 8 months ago
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Yogita Ingle 6 years, 8 months ago
- Mole fraction can be defined as the ratio of number of moles of the component in the solution to the total number of moles of all components in the solution.
- It is denoted by the alphabet x and subscript written on the right hand side of x denotes the component of which mole fraction is being calculated.
- Mathematically, Mole fraction of a component =number of moles of the component / total number of moles of all components
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Yogita Ingle 6 years, 8 months ago
Grignard reagents: Alkyl magnesium halides (RMgX) are called Grignard reagents.
Preparation of Grignard reagents: When a solution of alkyl halide (R—X) in ether is allowed to stand over magnesium turning for some time then metal gradually dissolves. In this reaction alkyl magnesium halide is formed. This compound is called Grignard reagent.
R-X + Mg {tex}\xrightarrow{dry\;ether}{/tex} R-Mg-X
Posted by Vanya Singh 6 years, 8 months ago
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Yogita Ingle 6 years, 8 months ago
Osmotic pressure is the pressure that we need to apply to stop the flow of solvent molecules from a dilute solution to a concentrated solution through a semi-permeable membrane. Now, the above statement has many terms that need a thorough explanation.
We have observed that when we separate a dilute solution from a concentrated solution of the same type by a membrane, the solvent molecules flow from the dilute solution to the concentrated solutions. This movement continues until it reaches an equilibrium. This process of flow of solvent molecules due to the difference in concentration is osmosis.
Posted by Madhvi Tiwari 6 years, 8 months ago
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Yogita Ingle 6 years, 8 months ago
Step-1. Formic acid may be reduced to methanol by reacting it with lithium aluminium hydride.
2. Methanol on reaction with PCl5 or SOCl2 will give methyl chloride.
CH3OH + SOCl2 = CH3Cl + HCl + SO2
3. Methyl chloride on reaction with KCN will form CH3CN, which on hydrolysis yields acetic acid.
Posted by Sandeep Yadav 6 years, 8 months ago
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Yogita Ingle 6 years, 8 months ago
Ambident nucleophiles: The nucleophiles with two nucleophilic centres are called ambident nucleophile.For example cyanide act as ambident nucleophilies.
There are two nucleophiles centres, at carbon and nitrogen in cyanide ion (C ≡ N:). They can react through either of these centres. Depending on the reagent and the reaction conditions, the reaction may take place predominantly at one of these centres.

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