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Ask QuestionPosted by Rahul Nehwal 6 years, 7 months ago
- 1 answers
Gaurav Seth 6 years, 7 months ago
Raoult’s law as special case of Henry’s law

- At a given temperature liquids vaporize. At equilibrium the pressure exertedby the vapour of the liquid over the liquidphase is referred to as vapour pressure.
- According to Raoult’s law, vapour pressure of a volatile component in a given solution ca be defined by pi = pi 0 xi
- In an answer of a gas in a fluid one of the segments is volatile to the point that it exists as a gas and solvency is given by Henry's law which expresses that p = KH x
- Comparing both the equations we get that partial pressure of the volatile component or gas is directly proportional to its mole fraction in solution. Proportionality constant KH differs from p10
- Therefore, Raoult's law turns into a unique instance of Henry’s law in which KH get to be equivalent to p10.
Posted by Vivek Mishra 6 years, 7 months ago
- 3 answers
Gaurav Seth 6 years, 7 months ago
We know,

Kf = Molal depression constant ( 5.12 K Kg/mol)
wB = weight of the solute
wA = weight of the solvent
MB = Observed molar mass of the solute.
Substituting the values we get,

Calculated molecular weight of phenol = 12 x 6 + 1 x 5 + 16 + 1
= 94 g
The association of phenol can be represented as:

Here, x is the degree of association.
The total number of particles after association
Now,

Hence, the fraction of phenol dimerized = 73%
Gaurav Seth 6 years, 7 months ago
Question:
Phenol associates in benzene to certain extent to form a dimer. A solution that is containing 20 x 10-3kg of phenol dissolved in 1 kg of benzene has its freezing point decreased by 0.61 K. Calculate the fraction of phenol that has dimerised.
Solution:
∆ Tf = Kf wB 1000/ wA MB
0.69 = 5.12 x 20 x 10^-3 x 10^3 / 1 x MB
MB = 5.12 x 20 / 1 x 0.69
Molecular weight of phenol = 94g
Calculated M . W / observed M . W = No. of particles after association/ No. of particles before association
94 / 148.4 = 1 - x/2 / 1
x = 0.73 per mole
Fraction of C6H5OH = 0.73 x 100 = 73%
Posted by Rajni Sharma 6 years, 7 months ago
- 1 answers
Gaurav Seth 6 years, 7 months ago
Cellulose acetate, potassium ferrocyanide, etc. are used as semipermeable membrane for carrying out reverse osmosis.
Posted by Priyanshi Jaiswal 6 years, 7 months ago
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Antriksh Bohara 6 years, 7 months ago
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Gaurav Seth 6 years, 7 months ago
Since in this problem ‘k’ is not given so we have to find out.
Applying Henry’s equation,S = k P
k= S/P = 6.8 X 10-4 mol L-1 = 6.8 X 10-4 mol L-1
1
So the solubility of N2 at 0.78 atm:
S= (6.8 X 10-4 mol L-1 ) (0.78 atm) = 5.3 x10-4 M
Posted by Gursharn Kaur 6 years, 7 months ago
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Nishu Sahu 6 years, 7 months ago
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Gursharn Kaur 6 years, 7 months ago
Yogita Ingle 6 years, 7 months ago
Ortho- describes a molecule with substituents at the 1 and 2 positions on an aromatic compound. In other words, the substituent is adjacent or next to the primary carbon on the ring.
The symbol for ortho- is o- or 1,2-<name of compound>
Para-
Para- describes a molecule with substituents at the 1 and 4 positions on an aromatic compound. In other words, the substituent is directly opposite the primary carbon of the ring.
The symbol for para- is p- or 1,4-<name of compound>
Abhi Saini 6 years, 7 months ago
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Gursharn Kaur 6 years, 7 months ago
Sinchana Malagond 6 years, 7 months ago
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Shubham Prajapati 6 years, 7 months ago
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Harsh Kaushik 6 years, 7 months ago
Yogita Ingle 6 years, 7 months ago
In the electrochemical cell a salt bridge performs the following functions:
a) It allows the flow of current by completing the circuit.
b) It maintains electrical neutrality.
Posted by Sanjeet Barnwal 6 years, 7 months ago
- 2 answers
Aisha Patel 6 years, 7 months ago
Yogita Ingle 6 years, 7 months ago
Treatment of a primary alkyl halide or pseudohalide with an alkali metal halide (e.g. KF, KI) leads to replacement of the halogen via an SN2 Reaction. this us called Finkelstein Reaction.
Posted by Ayushi Yadav 6 years, 7 months ago
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S.....Sharma☺??? .. 6 years, 7 months ago
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Hemant Bhardwaj 6 years, 7 months ago
Yogita Ingle 6 years, 7 months ago
Gibbs free energy is the energy needed to create a system out of nothing in an environment at both constant pressure and constant temperature.
It is defined mathematically by the equation.
G = H - TS
Where H = heat content, S = entropy of the system, T = absolute temperature
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Sourabh Singh 6 years, 7 months ago
Sourabh Singh 6 years, 7 months ago
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Yogita Ingle 6 years, 7 months ago
The diazonium salts (di refers to ‘two’, azo is indicative of ‘nitrogen’ and ium implies that it is cationic in nature), or diazonium compounds, are the class of organic compounds with general formula R−N2+X− where X is an organic or inorganic anion (for example, Cl–, Br–, BF4–, etc.) and R is an alkyl or aryl group. Hence, they have two nitrogen atoms with one being charged. Benzenediazonium chloride (C6H5N2+Cl–), benzenediazonium hydrogensulphate (C6H5N2+HSO4–), etc. are some of the examples of the diazonium salt.
- They are ionic in nature.
- They are water soluble.
- Aryl diazonium salts are colorless crystalline solids.

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Sayeda Iram Ateeq 6 years, 7 months ago
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