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The total heat content of a system at constant pressure is equal to the sum of the internal energy and PV. This is called the enthalpy of a system which is represented by H.
Note that enthalpy is also called as heat content.
H = U + pv
Enthalpy which depends on the three state functions: internal energy, pressure and volume.Hence it is also a state function.
Enthalpy of a substance cannot be measured, but change in enthalpy can be measured.
Change in enthalpy = Enthalpy of products - Enthalpy of reactants
∆H = HP-HR
From the first law of thermodynamics
∆U =qp-P∆V
qp =heat absorbed by the system
-P∆V=work done by the system.
For finite changes at constant pressure,
∆H= ∆U+∆(PV)
∆H=∆U+P∆V (∵ P is constant )
∆H=qp
∆H=-Ve for exothermic reactions
∆H=+Ve for endothermic reactions.
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Deepika Tiwari 7 years, 6 months ago
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