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Ask QuestionPosted by Anjani Kumar 6 years, 9 months ago
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Yogita Ingle 6 years, 9 months ago
The acidic strength of phenols is affected by the presence of substituents on the ring.
An electron-withdrawing group increases the acidic strength by greater dispersal of the negative charge on the phenoxide ion by inductive effect (-I) or by resonance (-R) effect.
An electron-donating group decreases the acidic strength due to (+I) or (+R) or both.
Halogens have +R and -I effects, but the -I effect is more dominant.
Therefore, all halophenols are more acidic(except p-fluorophenol) than phenol itself.
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Yogita Ingle 6 years, 9 months ago
White phosphorus is made up of discrete P4 tetrahedra which are subjected to very high angular strain as the angles is 60 degrees.
Red phosphorus is a polymer of P4 tetrahedra, which has much less angular strain.
This high angular strain makes white phosphorus unstable and highly reactive.
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Anjani Kumar 6 years, 9 months ago
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