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Yogita Ingle 6 years, 3 months ago
Organic compounds mainly contains carbon and hydrogen. Hydrocarbon chain is hydrophobic or oleophilic. Polar hydrocarbons dissolve in water due to formation of hydrogen bonds with water.
As hydrocarbon part increases, solubility in water decreases due to increase in oleophilic part. Thus hydrocarbons are miscible in organic solvents.
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Le Chatelier’s principles, also known as the equilibrium law, are used to predict the effect of some changes on a system in chemical equilibrium (such as the change in temperature or pressure). The principle is named after the French chemist Henry Louis Le Chatelier.
Le Chatelier said that equilibrium adjusts the forward and backward reactions in such a way to accept the changes affecting the equilibrium conditions.
When factors like concentration, pressure, temperature, inert gases that affect equilibrium are changed, the equilibrium will shift in that direction where the effects caused by these changes are nullified.
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The enthalpy change associated with the removal of the first electron from an isolated gaseous atom in its ground state is called first ionization enthalpy.
Ionization enthalpy depends on the following factors:
- Penetration effect
- Shielding effect
- Electronic configuration
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Nitrogen, sulphur, halogens and phosphorus present in an organic compound are detected by Lassaignes test. The elements present in the compound are converted from covalent form to ionic form by fusing the compound with sodium metal.
Na + C + N {tex}\xrightarrow{Heat}{/tex} NaH
2Na + S {tex}\xrightarrow{Heat}{/tex} Na2S
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Polar covalent bonding is a type of chemical bond where a pair of electrons is unequally shared between two atoms.
Example: Hydrogen chloride (HCl) molecule.
The bonding of hydrogen and chlorine atoms leans more towards Cl atom because Cl is more electronegative in nature than the hydrogen. Thus the shared pair of electrons lies not exactly in between the bond but lean towards chlorine. Due to this Cl atom acquire a slight negative charge, and H atom acquire slight positive charge.
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