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Preparation of washing soda by solvay’s process
- The Solvay process is extensively used for industrial preparation of sodium carbonate (soda ash). The process is named after Ernest Solvay who developed the process during the 1860s.
- Carbon dioxide reacts with the dissolved ammonia to form ammonium carbonate followed by ammonium hydrogen carbonate.
2NH3 +H2O + CO2→ (NH4)2CO3
(Ammonia) (Ammonium Carbonate)
(NH4)2CO3 + H2O + CO2 → NH4HCO3
(Ammonium Carbonate) (Ammonium hydrogen carbonate)
NH4HCO3 + NaCl → NH4Cl + NaHCO3
Sodium hydrogen carbonate crystal separates. These are heated to give sodium carbonate.
2 NaHCO3→ Na2CO3 + CO2 + H2O
But this process cannot be used to prepare potassium due to the high solubility of potassium bicarbonate and hence difficult to be precipitated by adding ammonium bicarbonate to a saturated solution of potassium
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Ekta E 6 years, 1 month ago
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