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H2O2 is very unstable and highly reactive. Its vapours are explosive in nature at normal temperature and pressures. It decomposes easily and can lead to hazardous reactions. Hence very high care should be taken for the long time storage of H2O2.
It should be stored in cool, dry, well-ventilated area and away from any flammable or combustible substances. It should be stored in non-reactive containers. As it breaks down quickly when exposed to light, it should be stored in an opaque container (brown bottles).
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A free radical reaction is any chemical reaction which involves free radicals.
In the mechanism of a chemical reaction if the attacking reagent is free radical then that reaction mechanism is called free radical mechanism.
Example: Halogination of alkanes
Posted by Prince Kumar 6 years, 11 months ago
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Yogita Ingle 6 years, 11 months ago
Organic Chemistry It is a branch of chemistry which deals with the study of carbon-based compounds. It mainly applies to the study of the behavior, characteristics, compositions and the properties of the organic compounds. It is also known as The Chemistry of Life.
Inorganic Chemistry A branch of chemistry that deals with the study of metals and gaseous matter or materials which do not contain carbon as an element in it is called Inorganic chemistry. It is opposite side of Organic Chemistry.
Physical Chemistry The combined study of using physics and chemistry to explain chemical systems is called Physical chemistry. This branch relates to the physical properties along with the structure of matter and energy. The sub-branches coming under this field are quantum physics and thermodynamics.
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Postulates of Valence Bond Theory
- The overlapping of two half-filled valence orbitals of two different atoms results in the formation of the covalent bond. The overlapping causes the electron density between two bonded atoms to increase. This gives the property of stability to the molecule.
- In case the atomic orbitals possess more than one unpaired electron, more than one bond can be formed and electrons paired in the valence shell cannot take part in such a bond formation.
- A covalent bond is directional. Such a bond is also parallel to the region of overlapping atomic orbitals.
- Based on the pattern of overlapping, there are two types of covalent bonds: sigma bond and a pi bond. The covalent bond formed by sidewise overlapping of atomic orbitals is known as pi bond whereas the bond formed by overlapping of atomic orbital along the inter nucleus axis is known as a sigma bond.
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Polarizing power can be defined as the ability of a cation to attract the electron cloud towards itself. Polarising power is proportional to charge/size. If the size of the cation is small, it will have more charge density and hence its polarising power increases whereas in anions with increase in its size polarisability increases. Also, higher the charge on a cation more is its polarizing power while higher the charge of an anion more is its polarisability.
The region of space around the nucleus which describes the probability of finding an electron of given energy in terms of dots is called an electron cloud.
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