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| Sigma Bond | Pi Bond |
| During sigma bond formation overlapping orbitals can either be one hybrid orbital and a single pure orbital, or two pure orbitals and two hybrid orbitals. | During pi bond formation overlapping orbitals must be two unhybridized orbitals. |
| Sigma bonds are known to exist independently and allow free rotation. | Pi-bonds must always exist along with sigma bond and the rotation is restricted. |
| Sigma bonds are stronger bonds. | Pi bonds are usually less powerful compared to sigma bonds. |
| Sigma bonds are formed first when atoms interact. | Pi bonds between two atoms are formed after sigma bonds are formed between them. |
| During the bonding between two given atoms, Only one sigma bond is formed. | Here two pi bonds can exist between two atoms. |
| Sigma bonds are known to have cylindrical charge symmetry around the axis of the bond. | No symmetry exists in pi bonds. |
| Atoms with sigma bonds can be highly reactive. | Atoms with pi bonds are not as reactive in nature when compared to those with only sigma bonds. |
| Sigma bond can be used to determine the shapes of molecules. | Pi bond cannot be used for the same purpose. |
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