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Sulphur shows greater catination than oxygen.How?

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Sulphur shows greater catination than oxygen.How?

    • Posted by Harshil Parashar 4 years, 2 months ago

    CBSE > Class 12 > Chemistry
    • 10 answers

    Arjun Kumar Yadav 4 years, 2 months ago

    Because sulphur is polyatomic or oxygen is diatomic

    1Thank You

    Harshil Parashar 4 years, 2 months ago

    Yupp! Vaishnavi thank u ?

    1Thank You

    Avantika Tayal 4 years, 2 months ago

    Hey shreya i got what u said.actually i typed a little wrong.the o-o bond at room temp is weeker than sulphur.plzz do correct this in your mind. Secondly u mentioned lone pair ...basically this bond is weeker just because of lone pair on oxygen which causes repulsions and makes its bond dissociation enthalpy less than that of sulphur...and hence does not show catenation... Hope this clears your doubt...

    1Thank You

    Harshil Parashar 4 years, 2 months ago

    Thank u so much .Ur reply releaved me. About my text? thanks again shruti?

    2Thank You

    Manjay Jha 4 years, 2 months ago

    Ooops! Sorry, Shreya i didn't saw your text. Btw what you said about oxygen is absolutely correct but in some cases we go for more appropriate answers !

    2Thank You

    Harshil Parashar 4 years, 2 months ago

    I am asking is what i have texted abt lone pair is correct or not. I am not asking abt.sulphur i am asking abt oxygen..hope u understand

    1Thank You

    Manjay Jha 4 years, 2 months ago

    Sulphur shows greater catination cuz' it has vacant d orbit and bond between S-S at room temperature is much weaker leads to formation of catination.

    2Thank You

    Harshil Parashar 4 years, 2 months ago

    What u said i got ur point. But isn't it about lone pair presence on oxygen due to which repulsion occurs.If not then why ..pplz help me out this

    1Thank You

    Avantika Tayal 4 years, 2 months ago

    Oxygen due to its small size,highest electronegativity and absence of vacant d orbital do not form catenated chain of oxocompounds.but sulphur has vacant d orbital.moreover s-s bond at room tp is weeker so exist as catnated compounds.

    2Thank You

    Killer Xmarty 4 years, 2 months ago

    Because of increasing bond enthalpy???

    1Thank You

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