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out of chlorobenzene and benzyl chloride …

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out of chlorobenzene and benzyl chloride which one gets easily hydrolysed by aqueous NaOH and why?

    • Posted by Varsha Lachhwani 6 years, 9 months ago

    CBSE > Class 12 > Chemistry
    • 1 answers

    Prince Jaat 6 years, 9 months ago

    Chlorobenzene does not undergo hydrolysis readily at room temperature because of the stability of the phenyl cation. The phenyl cation is unstable than the benzyl cation because of the high bond energy of the aromatic C-H bond. Benzyl carbocation being resonance stabilised, can easily release the Cl and thus get hydrolysed.

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