{"id":4698,"date":"2016-05-17T11:49:00","date_gmt":"2016-05-17T06:19:00","guid":{"rendered":"http:\/\/mycbseguide.com\/blog\/ncert-solutions-class-11-chemistry-organic-chemistry-some-basic-principles-part-2\/"},"modified":"2018-10-22T18:21:07","modified_gmt":"2018-10-22T12:51:07","slug":"ncert-solutions-class-11-chemistry-organic-chemistry-some-basic-principles-part-2","status":"publish","type":"post","link":"https:\/\/mycbseguide.com\/blog\/ncert-solutions-class-11-chemistry-organic-chemistry-some-basic-principles-part-2\/","title":{"rendered":"NCERT Solutions class-11 Chemistry Organic Chemistry Some Basic Principles Part-2"},"content":{"rendered":"<p>21.Discuss the chemistry of Lassaigne&#8217;s test.<\/p>\n<p>22. Differentiate between the principle of estimation of nitrogen in an organic compound by (i) Dumas method and (ii) Kjeldahl&#8217;s method.<\/p>\n<p>23. Discuss the principle of estimation of halogens, sulphur and phosphorus present in an organic compound.<\/p>\n<p>24. Explain the principle of paper chromatography.<\/p>\n<p>25. Why is nitric acid added to sodium extract before adding silver nitrate for testing halogens?<\/p>\n<p>26. Explain the reason for the fusion of an organic compound with metallic sodium for testing nitrogen, sulphur and halogens.<\/p>\n<p>27. Name a suitable technique of separation of the components from a mixture of calcium sulphate and camphor.<\/p>\n<p>28.Explain, why an organic liquid vaporises at a temperature below its boiling point in its steam distillation?<\/p>\n<p>29. Will <img decoding=\"async\" style=\"height: 24px; width: 38px;\" src=\"https:\/\/media-mycbseguide.s3.amazonaws.com\/images\/static\/ncert\/11\/chemistry\/ch12\/image191.png\" \/> give white precipitate of AgCl on heating it with silver nitrate? Give reason for your answer.<\/p>\n<p>30. Why is a solution of potassium hydroxide used to absorb carbon dioxide evolved during the estimation of carbon present in an organic compound?<\/p>\n<p>31. Why is it necessary to use acetic acid and not sulphuric acid for acidification of sodium extract for testing sulphur by lead acetate test?<\/p>\n<p>32. An organic compound contains 69% carbon and 4.8% hydrogen, the remainder being oxygen. Calculate the masses of carbon dioxide and water produced when 0.20 g of this substance is subjected to complete combustion.<\/p>\n<p>33. A sample of 0.50 g of an organic compound was treated according to Kjeldahl&#8217;s method. The ammonia evolved was absorbed in 50 mL of 0.5 M<img decoding=\"async\" style=\"height: 24px; width: 51px;\" src=\"https:\/\/media-mycbseguide.s3.amazonaws.com\/images\/static\/ncert\/11\/chemistry\/ch12\/image199.png\" \/> . The residual acid required 60 mL of 0.5 M solution of NaOH for neutralisation. Find the percentage composition of nitrogen in the compound.<\/p>\n<p>34.0.3780 g of an organic chloro compound gave 0.5740 g of silver chloride in Carius estimation. Calculate the percentage of chlorine present in the compound.<\/p>\n<p>35. In the estimation of sulphur by Carius method, 0.468 g of an organic sulphur compound afforded 0.668 g of barium sulphate. Find out the percentage of sulphur in the given compound.<\/p>\n<p>36. In the organic compound<img decoding=\"async\" style=\"height: 24px; width: 230px;\" src=\"https:\/\/media-mycbseguide.s3.amazonaws.com\/images\/static\/ncert\/11\/chemistry\/ch12\/image210.png\" \/> , the pair of hydridised orbitals involved in the formation of: <img decoding=\"async\" style=\"height: 24px; width: 63px;\" src=\"https:\/\/media-mycbseguide.s3.amazonaws.com\/images\/static\/ncert\/11\/chemistry\/ch12\/image211.png\" \/> bond is:<\/p>\n<p>(a) <img decoding=\"async\" style=\"height: 27px; width: 323px;\" src=\"https:\/\/media-mycbseguide.s3.amazonaws.com\/images\/static\/ncert\/11\/chemistry\/ch12\/image212.png\" \/><\/p>\n<p>37. In the Lassaigne&#8217;s test for nitrogen in an organic compound, the Prussian blue colour is obtained due to the formation of:<\/p>\n<p>(a) <img decoding=\"async\" style=\"height: 31px; width: 531px;\" src=\"https:\/\/media-mycbseguide.s3.amazonaws.com\/images\/static\/ncert\/11\/chemistry\/ch12\/image217.png\" \/><\/p>\n<p>38.Which of the following carbocation is most stable?<\/p>\n<p>(a) <img decoding=\"async\" style=\"height: 33px; width: 99px;\" src=\"https:\/\/media-mycbseguide.s3.amazonaws.com\/images\/static\/ncert\/11\/chemistry\/ch12\/image220.png\" \/><\/p>\n<p>(b) <img decoding=\"async\" style=\"height: 33px; width: 64px;\" src=\"https:\/\/media-mycbseguide.s3.amazonaws.com\/images\/static\/ncert\/11\/chemistry\/ch12\/image221.png\" \/><\/p>\n<p>(c) <img decoding=\"async\" style=\"height: 33px; width: 96px;\" src=\"https:\/\/media-mycbseguide.s3.amazonaws.com\/images\/static\/ncert\/11\/chemistry\/ch12\/image222.png\" \/><\/p>\n<p>(d) <img decoding=\"async\" style=\"height: 33px; width: 124px;\" src=\"https:\/\/media-mycbseguide.s3.amazonaws.com\/images\/static\/ncert\/11\/chemistry\/ch12\/image223.png\" \/><\/p>\n<p>39. The best and latest technique for isolation, purification and separation of organic compounds is:<\/p>\n<p>(a) Crystallisation<\/p>\n<p>(b) Distillation<\/p>\n<p>(c) Sublimation<\/p>\n<p>(d) Chromatography<\/p>\n<p>40. The reaction:<\/p>\n<p><img decoding=\"async\" style=\"height: 25px; width: 266px;\" src=\"https:\/\/media-mycbseguide.s3.amazonaws.com\/images\/static\/ncert\/11\/chemistry\/ch12\/image224.png\" \/><\/p>\n<p>is classified as:<\/p>\n<p>(a) electrophilic substitution<\/p>\n<p>(b) nucleophilic substitution<\/p>\n<p>(c) elimination<\/p>\n<p>(d) addition<\/p>\n","protected":false},"excerpt":{"rendered":"<p>21.Discuss the chemistry of Lassaigne&#8217;s test. 22. Differentiate between the principle of estimation of nitrogen in an organic compound by (i) Dumas method and (ii) Kjeldahl&#8217;s method. 23. Discuss the principle of estimation of halogens, sulphur and phosphorus present in an organic compound. 24. Explain the principle of paper chromatography. 25. Why is nitric acid &#8230; <a title=\"NCERT Solutions class-11 Chemistry Organic Chemistry Some Basic Principles Part-2\" class=\"read-more\" href=\"https:\/\/mycbseguide.com\/blog\/ncert-solutions-class-11-chemistry-organic-chemistry-some-basic-principles-part-2\/\" aria-label=\"More on NCERT Solutions class-11 Chemistry Organic Chemistry Some Basic Principles Part-2\">Read more<\/a><\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[47,281],"tags":[],"class_list":["post-4698","post","type-post","status-publish","format-standard","hentry","category-cbse-class-11","category-ncert-solutions"],"yoast_head":"<!-- This site is optimized with the Yoast SEO plugin v26.0 - https:\/\/yoast.com\/wordpress\/plugins\/seo\/ -->\n<title>NCERT Solutions class-11 Chemistry Organic Chemistry Some Basic Principles Part-2 | myCBSEguide<\/title>\n<meta name=\"robots\" content=\"index, follow, max-snippet:-1, max-image-preview:large, max-video-preview:-1\" \/>\n<link rel=\"canonical\" href=\"https:\/\/mycbseguide.com\/blog\/ncert-solutions-class-11-chemistry-organic-chemistry-some-basic-principles-part-2\/\" \/>\n<meta property=\"og:locale\" content=\"en_US\" \/>\n<meta property=\"og:type\" content=\"article\" \/>\n<meta property=\"og:title\" content=\"NCERT Solutions class-11 Chemistry Organic Chemistry Some Basic Principles Part-2 | myCBSEguide\" \/>\n<meta property=\"og:description\" content=\"21.Discuss the chemistry of Lassaigne&#8217;s test. 22. 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