{"id":4374,"date":"2016-05-14T11:49:00","date_gmt":"2016-05-14T06:19:00","guid":{"rendered":"http:\/\/mycbseguide.com\/blog\/ncert-solutions-class-12-chemistry-aldehydes-ketones-and-carboxylic-acid-part-2\/"},"modified":"2018-10-22T15:40:53","modified_gmt":"2018-10-22T10:10:53","slug":"ncert-solutions-class-12-chemistry-aldehydes-ketones-and-carboxylic-acid-part-2","status":"publish","type":"post","link":"https:\/\/mycbseguide.com\/blog\/ncert-solutions-class-12-chemistry-aldehydes-ketones-and-carboxylic-acid-part-2\/","title":{"rendered":"NCERT Solutions class 12 Chemistry aldehydes ketones and carboxylic acid part 2"},"content":{"rendered":"<div id=\"ez-toc-container\" class=\"ez-toc-v2_0_76 counter-hierarchy ez-toc-counter ez-toc-grey ez-toc-container-direction\">\n<div class=\"ez-toc-title-container\">\n<p class=\"ez-toc-title\" style=\"cursor:inherit\">Table of Contents<\/p>\n<span class=\"ez-toc-title-toggle\"><a href=\"#\" class=\"ez-toc-pull-right ez-toc-btn ez-toc-btn-xs ez-toc-btn-default ez-toc-toggle\" aria-label=\"Toggle Table of Content\"><span class=\"ez-toc-js-icon-con\"><span class=\"\"><span class=\"eztoc-hide\" style=\"display:none;\">Toggle<\/span><span class=\"ez-toc-icon-toggle-span\"><svg style=\"fill: #999;color:#999\" xmlns=\"http:\/\/www.w3.org\/2000\/svg\" class=\"list-377408\" width=\"20px\" height=\"20px\" viewBox=\"0 0 24 24\" fill=\"none\"><path d=\"M6 6H4v2h2V6zm14 0H8v2h12V6zM4 11h2v2H4v-2zm16 0H8v2h12v-2zM4 16h2v2H4v-2zm16 0H8v2h12v-2z\" fill=\"currentColor\"><\/path><\/svg><svg style=\"fill: #999;color:#999\" class=\"arrow-unsorted-368013\" xmlns=\"http:\/\/www.w3.org\/2000\/svg\" width=\"10px\" height=\"10px\" viewBox=\"0 0 24 24\" version=\"1.2\" baseProfile=\"tiny\"><path d=\"M18.2 9.3l-6.2-6.3-6.2 6.3c-.2.2-.3.4-.3.7s.1.5.3.7c.2.2.4.3.7.3h11c.3 0 .5-.1.7-.3.2-.2.3-.5.3-.7s-.1-.5-.3-.7zM5.8 14.7l6.2 6.3 6.2-6.3c.2-.2.3-.5.3-.7s-.1-.5-.3-.7c-.2-.2-.4-.3-.7-.3h-11c-.3 0-.5.1-.7.3-.2.2-.3.5-.3.7s.1.5.3.7z\"\/><\/svg><\/span><\/span><\/span><\/a><\/span><\/div>\n<nav><ul class='ez-toc-list ez-toc-list-level-1 eztoc-toggle-hide-by-default' ><li class='ez-toc-page-1 ez-toc-heading-level-2'><a class=\"ez-toc-link ez-toc-heading-1\" href=\"https:\/\/mycbseguide.com\/blog\/ncert-solutions-class-12-chemistry-aldehydes-ketones-and-carboxylic-acid-part-2\/#NCERT_Class_12_Chemistry_Chapter-wise_Solutions\" >NCERT Class 12 Chemistry Chapter-wise Solutions<\/a><\/li><li class='ez-toc-page-1 ez-toc-heading-level-2'><a class=\"ez-toc-link ez-toc-heading-2\" href=\"https:\/\/mycbseguide.com\/blog\/ncert-solutions-class-12-chemistry-aldehydes-ketones-and-carboxylic-acid-part-2\/#CHAPTER_TWELVE_ALDEHYDES_KETONES_AND_CARBOXYLIC_ACIDS\" >CHAPTER TWELVE ALDEHYDES, KETONES AND CARBOXYLIC ACIDS<\/a><\/li><li class='ez-toc-page-1 ez-toc-heading-level-2'><a class=\"ez-toc-link ez-toc-heading-3\" href=\"https:\/\/mycbseguide.com\/blog\/ncert-solutions-class-12-chemistry-aldehydes-ketones-and-carboxylic-acid-part-2\/#NCERT_Solutions_class_12_Chemistry_aldehydes_ketones_and_carboxylic_acid_part_2\" >NCERT Solutions class 12 Chemistry aldehydes ketones and carboxylic acid part 2<\/a><\/li><li class='ez-toc-page-1 ez-toc-heading-level-2'><a class=\"ez-toc-link ez-toc-heading-4\" href=\"https:\/\/mycbseguide.com\/blog\/ncert-solutions-class-12-chemistry-aldehydes-ketones-and-carboxylic-acid-part-2\/#NCERT_Solutions_class_12_Chemistry\" >NCERT Solutions class 12 Chemistry<\/a><\/li><li class='ez-toc-page-1 ez-toc-heading-level-2'><a class=\"ez-toc-link ez-toc-heading-5\" href=\"https:\/\/mycbseguide.com\/blog\/ncert-solutions-class-12-chemistry-aldehydes-ketones-and-carboxylic-acid-part-2\/#CBSE_app_for_Students\" >CBSE app for Students<\/a><\/li><\/ul><\/nav><\/div>\n<p>NCERT Solutions class 12 Chemistry aldehydes ketones and carboxylic acid part 2 solutions are available in PDF format for free download. These ncert book chapter wise questions and answers are very helpful for CBSE board exam. CBSE recommends NCERT books and most of the questions in CBSE exam are asked from NCERT text books. Class 12 Chemistry chapter wise NCERT solution for Chemistry part 1 and Chemistry part 2 for all the chapters can be downloaded from our website and myCBSEguide mobile app for free.<\/p>\n<p style=\"text-align: center;\"><strong>Download\u00a0<a href=\"https:\/\/mycbseguide.com\/downloads\/cbse-class-12-chemistry\/1267\/ncert-solutions\/5\/\">\u00a0\u00a0NCERT solutions for aldehydes ketones and carboxylic acid part 2\u00a0<\/a>as PDF.<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignright\" src=\"https:\/\/media-mycbseguide.s3.ap-south-1.amazonaws.com\/images\/blog\/Class%2012%20Chemistry%20Book%20in%20English.jpg\" alt=\"NCERT Solutions class 12 Chemistry aldehydes ketones and carboxylic acid part 2\" width=\"123\" height=\"157\" \/><\/p>\n<h2><span class=\"ez-toc-section\" id=\"NCERT_Class_12_Chemistry_Chapter-wise_Solutions\"><\/span><strong>NCERT Class 12 Chemistry Chapter-wise Solutions<\/strong><span class=\"ez-toc-section-end\"><\/span><\/h2>\n<ul>\n<li>\u00a01 \u2013 The Solid State<\/li>\n<li>2 \u2013 Solutions<\/li>\n<li>3 \u2013 Electrochemistry<\/li>\n<li>4 \u2013 Chemical Kinetics<\/li>\n<li>5 \u2013 Surface Chemistry<\/li>\n<li>6 \u2013 General Principles and Processes of Isolation of Elements<\/li>\n<li>7 \u2013 The p-Block Elements<\/li>\n<li>8 \u2013 The d-and f-Blocks Elements<\/li>\n<li>9 \u2013 Coordination Compounds<\/li>\n<li>10 \u2013 Haloalkanes and Haloarenes<\/li>\n<li>11 \u2013 Alcohols, Phenols and Ethers<\/li>\n<li>12 \u2013 Aldehydes, Ketones and Carboxylic Acids<\/li>\n<li>13 \u2013 Amines<\/li>\n<li>14 \u2013 Biomolecules<\/li>\n<li>15 \u2013 Polymers<\/li>\n<li>16 \u2013 Chemistry in Everyday Life<\/li>\n<\/ul>\n<h2><span class=\"ez-toc-section\" id=\"CHAPTER_TWELVE_ALDEHYDES_KETONES_AND_CARBOXYLIC_ACIDS\"><\/span><strong>CHAPTER TWELVE ALDEHYDES, KETONES AND CARBOXYLIC ACIDS<\/strong><span class=\"ez-toc-section-end\"><\/span><\/h2>\n<ul>\n<li>12.1 Nomenclature and Structure of Carbonyl Group<\/li>\n<li>12.2 Preparation of Aldehydes and Ketones<\/li>\n<li>12.3 Physical Properties<\/li>\n<li>12.4 Chemical Reacxtions<\/li>\n<li>12.5 Uses of Aldehydes and Ketones<\/li>\n<li>12.6 Nomenclature and Structure of Carboxyl Group<\/li>\n<li>12.7 Methods of Preparation of Carboxylic Acids<\/li>\n<li>12.8 Physical properties<\/li>\n<li>12.9 Chemical Reactions<\/li>\n<li>12.10 Uses of carboxylic Acids<\/li>\n<\/ul>\n<h2><span class=\"ez-toc-section\" id=\"NCERT_Solutions_class_12_Chemistry_aldehydes_ketones_and_carboxylic_acid_part_2\"><\/span>NCERT Solutions class 12 Chemistry aldehydes ketones and carboxylic acid part 2<span class=\"ez-toc-section-end\"><\/span><\/h2>\n<p style=\"text-align: justify;\">11. An organic compound (A) (molecular formula <img decoding=\"async\" style=\"height: 24px; width: 58px;\" src=\"https:\/\/media-mycbseguide.s3.amazonaws.com\/images\/static\/ncert\/12\/chemistry\/ch12\/image124.png\" \/>) was hydrolysed with dilute sulphuric acid to give a carboxylic acid (B) and an alcohol (C). Oxidation of (C) with chromic acid produced (B). (C) on dehydration gives but-1-ene.Write eQuations for the reactions involved<strong>. <\/strong><\/p>\n<p>12. Arrange the following compounds in increasing order of their property as indicated:<\/p>\n<p>(i) Acetaldehyde, Acetone, Di-<em>tert<\/em>-butyl ketone, Methyl <em>tert<\/em>-butyl ketone (reactivity towards HCN)<\/p>\n<p>(ii) <img decoding=\"async\" style=\"height: 27px; width: 165px;\" src=\"https:\/\/media-mycbseguide.s3.amazonaws.com\/images\/static\/ncert\/12\/chemistry\/ch12\/image127.png\" \/>, <img decoding=\"async\" style=\"height: 27px; width: 165px;\" src=\"https:\/\/media-mycbseguide.s3.amazonaws.com\/images\/static\/ncert\/12\/chemistry\/ch12\/image128.png\" \/>, <img decoding=\"async\" style=\"height: 24px; width: 136px;\" src=\"https:\/\/media-mycbseguide.s3.amazonaws.com\/images\/static\/ncert\/12\/chemistry\/ch12\/image129.png\" \/> (acid strength)<\/p>\n<p>(iii) Benzoic acid, 4-Nitrobenzoic acid, 3,4-Dinitrobenzoic acid, 4-Methoxybenzoic acid (acid strength)<\/p>\n<p>13. Give simple chemical tests to distinguish between the following pairs of compounds.<\/p>\n<p>(i) Propanal and Propanone<\/p>\n<p>(ii) Acetophenone and Benzophenone<\/p>\n<p>(iii) Phenol and Benzoic acid<\/p>\n<p>(iv) Benzoic acid and Ethyl benzoate<\/p>\n<p>(v) Pentan-2-one and Pentan-3-one<\/p>\n<p>(vi) Benzaldehyde and Acetophenone<\/p>\n<p>(vii) Ethanal and Propanal<\/p>\n<p>14. How will you prepare the following compounds from benzene? You may use any inorganic reagent and any organic reagent having not more than one carbon atom<\/p>\n<p>(i) Methyl benzoate<\/p>\n<p>(ii) <em>m<\/em>-Nitrobenzoic acid<\/p>\n<p>(iii) <em>p<\/em>-Nitrobenzoic acid<\/p>\n<p>(iv) Phenylacetic acid<\/p>\n<p>(v) <em>p<\/em>-Nitrobenzaldehyde.<\/p>\n<p>15. How will you bring about the following conversions in not more than two steps?<\/p>\n<p>(i) Propanone to Propene<\/p>\n<p>(ii) Benzoic acid to Benzaldehyde<\/p>\n<p>(iii) Ethanol to 3-Hydroxybutanal<\/p>\n<p>(iv) Benzene to <em>m<\/em>-Nitroacetophenone<\/p>\n<p>(v) Benzaldehyde to Benzophenone<\/p>\n<p>(vi) Bromobenzene to 1-Phenylethanol<\/p>\n<p>(vii) Benzaldehyde to 3-Phenylpropan-1-ol<\/p>\n<p>(viii) Benazaldehyde to \u03b1-Hydroxyphenylacetic acid<\/p>\n<p>(ix) Benzoic acid to <em>m<\/em>&#8211; Nitrobenzyl alcohol<\/p>\n<p>16. Describe the following:<\/p>\n<p>(i) Acetylation<\/p>\n<p>(ii) Cannizzaro reaction<\/p>\n<p>(iii) Cross aldol condensation<\/p>\n<p>(iv) Decarboxylation<\/p>\n<p>17. Complete each synthesis by giving missing starting material, reagent or products<\/p>\n<p>(i)<\/p>\n<p><img decoding=\"async\" id=\"Picture 114\" style=\"height: 58px; width: 144px;\" src=\"https:\/\/media-mycbseguide.s3.amazonaws.com\/images\/static\/ncert\/12\/chemistry\/ch12\/image166.jpg\" alt=\"14361951062405.jpg\" \/><\/p>\n<p>(ii)<\/p>\n<p><img decoding=\"async\" id=\"Picture 115\" style=\"height: 68px; width: 156px;\" src=\"https:\/\/media-mycbseguide.s3.amazonaws.com\/images\/static\/ncert\/12\/chemistry\/ch12\/image167.jpg\" alt=\"14361951071785.jpg\" \/><\/p>\n<p>(iii)<\/p>\n<p><img decoding=\"async\" id=\"Picture 116\" style=\"height: 35px; width: 172px;\" src=\"https:\/\/media-mycbseguide.s3.amazonaws.com\/images\/static\/ncert\/12\/chemistry\/ch12\/image168.jpg\" alt=\"14361951081124.jpg\" \/><\/p>\n<p>(iv)<\/p>\n<p><img decoding=\"async\" id=\"Picture 117\" style=\"height: 80px; width: 246px;\" src=\"https:\/\/media-mycbseguide.s3.amazonaws.com\/images\/static\/ncert\/12\/chemistry\/ch12\/image169.jpg\" alt=\"14361951087413.jpg\" \/><\/p>\n<p>(v)<\/p>\n<p><img decoding=\"async\" id=\"Picture 118\" style=\"height: 64px; width: 183px;\" src=\"https:\/\/media-mycbseguide.s3.amazonaws.com\/images\/static\/ncert\/12\/chemistry\/ch12\/image170.jpg\" alt=\"14361951093754.jpg\" \/><\/p>\n<p>(vi)<\/p>\n<p><img decoding=\"async\" id=\"Picture 119\" style=\"height: 65px; width: 161px;\" src=\"https:\/\/media-mycbseguide.s3.amazonaws.com\/images\/static\/ncert\/12\/chemistry\/ch12\/image171.jpg\" alt=\"14361951105269.jpg\" \/><\/p>\n<p>(vii)<\/p>\n<p><img decoding=\"async\" id=\"Picture 120\" style=\"height: 59px; width: 150px;\" src=\"https:\/\/media-mycbseguide.s3.amazonaws.com\/images\/static\/ncert\/12\/chemistry\/ch12\/image172.jpg\" alt=\"14361951111475.jpg\" \/><\/p>\n<p>(viii)<\/p>\n<p><img decoding=\"async\" id=\"Picture 121\" style=\"height: 41px; width: 186px;\" src=\"https:\/\/media-mycbseguide.s3.amazonaws.com\/images\/static\/ncert\/12\/chemistry\/ch12\/image173.jpg\" alt=\"14361951118959.jpg\" \/><\/p>\n<p>(ix)<\/p>\n<p><img decoding=\"async\" id=\"Picture 122\" style=\"height: 40px; width: 133px;\" src=\"https:\/\/media-mycbseguide.s3.amazonaws.com\/images\/static\/ncert\/12\/chemistry\/ch12\/image174.jpg\" alt=\"14361951125688.jpg\" \/><\/p>\n<p>(x)<\/p>\n<p><img decoding=\"async\" id=\"Picture 123\" style=\"height: 30px; width: 216px;\" src=\"https:\/\/media-mycbseguide.s3.amazonaws.com\/images\/static\/ncert\/12\/chemistry\/ch12\/image175.jpg\" alt=\"14361951132188.jpg\" \/><\/p>\n<p>(xi)<\/p>\n<p><img decoding=\"async\" id=\"Picture 4\" style=\"height: 40px; width: 149px;\" src=\"https:\/\/media-mycbseguide.s3.amazonaws.com\/images\/static\/ncert\/12\/chemistry\/ch12\/image176.jpg\" alt=\"14361951138927.jpg\" \/><br \/>\n18. Give plausible explanation for each of the following:<\/p>\n<p>(i) Cyclohexanone forms cyanohydrin in good yield but 2, 2, 6 trimethylcyclohexanone does not.<\/p>\n<p>(ii) There are two &#8211; <img decoding=\"async\" style=\"height: 24px; width: 35px;\" src=\"https:\/\/media-mycbseguide.s3.amazonaws.com\/images\/static\/ncert\/12\/chemistry\/ch12\/image188.png\" \/>groups in semicarbazide. However, only one is involved in the formation of semicarbazones.<\/p>\n<p>(iii) During the preparation of esters from a carboxylic acid and an alcohol in the presence of an acid catalyst, the water or the ester should be removed as soon as it is formed.<\/p>\n<p>19. An organic compound contains 69.77% carbon, 11.63% hydrogen and rest oxygen. The molecular mass of the compound is 86. It does not reduce Tollens&#8217; reagent but forms an addition compound with sodium hydrogensulphite and give positive iodoform test. On vigorous oxidation it gives ethanoic and propanoic acid. Write the possible structure of the compound.<\/p>\n<p>20. Although phenoxide ion has more number of resonating structures than carboxylate ion, carboxylic acid is a stronger acid than phenol. Why?<\/p>\n<h2><span class=\"ez-toc-section\" id=\"NCERT_Solutions_class_12_Chemistry\"><\/span>NCERT Solutions class 12 Chemistry<span class=\"ez-toc-section-end\"><\/span><\/h2>\n<p>NCERT Solutions Class 12 Chemistry PDF (Download) Free from myCBSEguide app and myCBSEguide website. Ncert solution class 12 Chemistry includes text book solutions from both part 1 and part 2. NCERT Solutions for CBSE Class 12 Chemistry have total 16 chapters. 12 Chemistry NCERT Solutions in PDF for free Download on our website. Ncert Chemistry class 12 solutions PDF and Chemistry ncert class 12 PDF solutions with latest modifications and as per the latest CBSE syllabus are only available in myCBSEguide NCERT Solutions class 12 Chemistry aldehydes ketones and carboxylic acid part 2<\/p>\n<h2><span class=\"ez-toc-section\" id=\"CBSE_app_for_Students\"><\/span>CBSE app for Students<span class=\"ez-toc-section-end\"><\/span><\/h2>\n<p>To download\u00a0NCERT Solutions for class 12\u00a0Chemistry, Physics, Biology, History, Political Science, Economics, Geography, Computer Science, Home Science, Accountancy, Business Studies and Home Science; do check myCBSEguide app or website. myCBSEguide provides sample papers with solution, test papers for chapter-wise practice, NCERT solutions, NCERT Exemplar solutions, quick revision notes for ready reference, CBSE guess papers and CBSE important question papers. Sample Paper all are made available through\u00a0<a href=\"https:\/\/play.google.com\/store\/apps\/details?id=in.techchefs.MyCBSEGuide&amp;referrer=utm_source%3Dmycbse_bottom%26utm_medium%3Dtext%26utm_campaign%3Dmycbseads\"><strong>the best app for CBSE students<\/strong><\/a>\u00a0and myCBSEguide website.<\/p>\n","protected":false},"excerpt":{"rendered":"<p>NCERT Solutions class 12 Chemistry aldehydes ketones and carboxylic acid part 2 solutions are available in PDF format for free download. These ncert book chapter wise questions and answers are very helpful for CBSE board exam. CBSE recommends NCERT books and most of the questions in CBSE exam are asked from NCERT text books. Class &#8230; <a title=\"NCERT Solutions class 12 Chemistry aldehydes ketones and carboxylic acid part 2\" class=\"read-more\" href=\"https:\/\/mycbseguide.com\/blog\/ncert-solutions-class-12-chemistry-aldehydes-ketones-and-carboxylic-acid-part-2\/\" aria-label=\"More on NCERT Solutions class 12 Chemistry aldehydes ketones and carboxylic acid part 2\">Read more<\/a><\/p>\n","protected":false},"author":1,"featured_media":-1,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[1434,281],"tags":[283,320,1342,216],"class_list":["post-4374","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-chemistry-cbse-class-12","category-ncert-solutions","tag-cbse-study-material","tag-chemistry","tag-class-12","tag-ncert-solutions"],"yoast_head":"<!-- This site is optimized with the Yoast SEO plugin v26.0 - https:\/\/yoast.com\/wordpress\/plugins\/seo\/ -->\n<title>Class 12 Chemistry aldehydes ketones and carboxylic acid<\/title>\n<meta name=\"description\" content=\"NCERT Solutions class 12 Chemistry aldehydes ketones and carboxylic acid part 2 in PDF format for free download. 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